Scientific Highlights

The fuel used for nuclear energy production is normally enclosed in zirconium-based cladding tubes that constitute the first barrier between the radioactive material and the environment. In water-moderated reactors, cladding tubes tend to corrode, generating hydrogen as side product. The study of the hydrogen embrittlement in zirconium alloys is of high relevance for the industry.

Depending on temperature, local hydrogen concentration, and local stress conditions, different hydrogen-induced embrittlement mechanisms can be active in the cladding material: in certain conditions hydrogen in solid solution might cause material softening through a mechanism known as hydrogen enhanced localized plasticity (HELP).

With the goal of determining the conditions necessary to activate the HELP effect in zirconium alloys, samples have been evaluated by different micro-mechanical and macro-mechanical techniques. Results highlight the importance of the interplay between solid solution hydrogen and hydrides on the hardness and yield point of the tested materials.

This work aimed to produce intermetallic samples of platinoid metals (active metal matrix) and lanthanides (co-metal) and via the method of Coupled Reduction, i.e. a thermal treatment of the combination of the lanthanide oxide and noble metal at high temperature, as high as 1100 °C, under a constant flow of H₂. We have demonstrated by means of several techniques, such as Scanning Electron Microscope, Energy Dispersive X-Ray Spectroscopy, Alpha Spectrometry and Radiographic Imaging, that this method, at defined experimental conditions (temperature, pressure and concentration) yields a metallic lanthanide thin film when using platinum as active metal matrix. Conversely, the formation of a bulk intermetallic compound was obtained when using Pd as matrix. Those systems will have applications in different nuclear physic and radiochemistry studies, such as irradiation targets for production of superheavy elements and for nuclear data determination.

An international group of researchers led by the Paul Scherrer Institute has carried out in-depth analyses of the climate impact of blue hydrogen. This is produced from natural gas, with the CO₂ resulting from the process captured and permanently stored. The study concludes that blue hydrogen can play a positive role in the energy transition – under certain conditions.

This highlight presents a successful, in-house developed integration of an Electron Beam Ion Source (EBIS) able to ionize gases to high charge states with a customized commercial MC-ICP-MS. The successful joining of the two ion flight paths is a milestone towards comprehensive routine analyses of solids, liquids, and gases using THE SAME MASS SPECTROMETER, the latter analyses free from atmospheric contamination. After implementation of an introduction system for gas mass spectrometry, routine analyses will comprise isotope ratio and relative abundance determinations of fission gases in used nuclear fuel. In addition to the unique versatility of the MC-EBIS-ICP-MS, inclusion of the EBIS furthers opens the little-studied field of mass spectrometry of highly charged ions.

Water boiling control evolution of natural geothermal systems is widely exploited in industrial processes due to the unique non-linear thermophysical behavior. Even though the properties of water both in the liquid and gas state have been extensively studied experimentally and by numerical simulations, there is still a fundamental knowledge gap in understanding the mechanism of the heterogeneous nucleate boiling controlling evaporation and condensation. In this study, the molecular mechanism of bubble nucleation at the hydrophilic and hydrophobic solid–water interface was determined by performing unbiased molecular dynamics simulations using the transition path sampling scheme. Analyzing the liquid to vapor transition path, the initiation of small void cavities (vapor bubbles nuclei) and their subsequent merging mechanism, leading to successively growing vacuum domains (vapor phase), has been elucidated. The simulations reveal the impact of the surface functionality on the adsorbed thin water molecules film structuring and the location of high probability nucleation sites.

After several years of loyal and reliable services during heavy duty operation in a reactor, nuclear fuel must be discharged and go into retirement. For Switzerland, the final place of retirement is planned to consist of a deep geological repository where the used nuclear fuel will be disposed. Before the repository is constructed, the used fuel will need to be stored in wet pools and/or dry storage casks.

During all this time, safe handling of the fuel will remain the top priority for operators and regulators. To gain better knowledge on the relevant phenomena which could potentially affect the fuel thermo-mechanics and safety characteristics during long storage periods as well as to allow predicting their evolution, simulation models are being developed at PSI within the DRYstars project.

A first milestone was recently achieved with the development of models coupled to state-of-the-art fuel performance codes for each of the three main categories of phenomena considered as having high safety relevance for storage, namely helium behaviour, creep behaviour and hydrogen behaviour.

NZZ am Sonntag  has picked up this highlight in its issue on March 7th, 2021: The highlight refers to the analysis performed in SCCER Joint Activity Scenarios and Modelling, where PSI-LEA performed the analysis of the energy transition pathways.