CNM - Publication Highlights

We report significant photoelectrochemical activity of Y-doped BiFeO₃ (Y-BFO) epitaxial thin films deposited on Nb:SrTiO₃ substrates. The Y-BFO photoanodes exhibit a strong dependence of the photocurrent values on the thickness of the films, and implicitly on the induced epitaxial strain.

The mobility of magnetic domains forms the link between the basic physical properties of a magnetic material and its global characteristics such as permeability and saturation field. Most commonly, surface domain structure are studied using magneto-optical Kerr microscopy. The limited information depth of approx. 20 nanometers, however, allows only for an indirect interpretation of the internal volume domain structures.

Coordination complexes of magnesium borohydride show promising properties as solid electrolytes for magnesium ion batteries and warrant a thorough microscopic description of factors governing their mobility properties. Here, the dynamics of Mg(BH₄)₂-diglyme_0.5 on the atomic level are investigated by means of quasielastic neutron scattering supported by density functional theory calculations and IR and NMR spectroscopy.

The Coulomb phase is an idealized state of matter whose properties are determined by factors beyond conventional consid- erations of symmetry, including global topology, conservation laws and emergent order. Theoretically, Coulomb phases occur in ice-type systems such as water ice and spin ice; in dimer models; and in certain spin liquids. However, apart from ice-type systems, more general experimental examples are very scarce.

The geometry of magnetic flux penetration in a high temperature superconductor at a buried interface was imaged using element-specific x-ray excited luminescence. We performed low tem- perature observation of the flux penetration in YBa₂Cu₃O_7–δ (YBCO) at a buried interface by imaging of the perpendicular magnetization component in square Permalloy (Py) mesostructures patterned superjacent to a YBCO film.

Using soft x-ray angle-resolved photoemission spectroscopy we probed the bulk electronic structure of T_d-MoTe₂. We found that on-site Coulomb interaction leads to a Lifshitz transition, which is essential for a precise description of the electronic structure. A hybrid Weyl semimetal state with a pair of energy bands touching at both type-I and type-II Weyl nodes is indicated by comparing the experimental data with theoretical calculations.

The Mermin–Wagner theorem has long told us that in two dimensions a continuous symmetry can be broken, allowing a finite order parameter, only at zero temperature. Now PSI theorist Bruce Normand, working with colleagues in Aachen, Amsterdam, Lausanne and Paris, has circumvented this rule. The team was considering the thermodynamics

We consider the finite-temperature phase diagram of the S=1/2 frustrated Heisenberg bilayer. Although this two-dimensional system may show magnetic order only at zero temperature, we demonstrate the presence of a line of finite-temperature critical points related to the line of first-order transitions between the dimer-singlet and -triplet regimes.

Magnetic skyrmions are vortex-like topological spin textures often observed to form a triangular-lattice skyrmion crystal in structurally chiral magnets with the Dzyaloshinskii-Moriya interaction. Recently, β-Mn structure-type Co-Zn-Mn alloys were identified as a new class of chiral magnet to host such skyrmion crystal phases, while β-Mn itself is known as hosting an elemental geometrically frustrated spin liquid.

The demonstration that applied pressure can substantially change – rather than merely tweak – the properties of a metal–organic quantum magnet indicates a route to designing quantum materials with tailored properties.

Solid deuterium (sD₂) is used as an efficient converter to produce ultracold neutrons (UCN). Itis known that the sD₂ must be sufficiently cold, of high purity and mostly in its ortho-state in order to guarantee long lifetimes of UCN in the solid from which they are extracted into vacuum.

We report an extraordinary pressure dependence of the magnetic interactions in the metal-organic system [CuF₂(H₂O)₂]₂ pyrazine. At zero pressure, this material realizes a quasi-two-dimensional spin-1/2 square-lattice Heisenberg antiferromagnet. By high-pressure, high-field susceptibility measurements we show that the dominant exchange parameter is reduced continuously by a factor of 2 on compression.

Experiments demonstrating the inversion of entire domain patterns in multiferroic crystals highlight just how versatile this class of materials is, and indicate a route to exploring novel functionalities.

GdPtBi and NdPtBi belong to the Heusler family of compounds and are conventional antiferromagnets below 9 and 2.1 K, respectively. We present evidence for magnetic-field–induced Weyl physics in these compounds, namely, a chiral anomaly (negative magnetoresistance) and an anomalous Hall effect (AHE) with a large anomalous Hall angle over a wide range of temperature. The AHE and chiral anomaly have a similar temperature dependence, indicating their common origin.

The inversion of inhomogeneous physical states has great technological importance; for example, active noise reduction relies on the emission of an inverted sound wave that interferes destructively with the noise of the emitter1, and inverting the evolution of a spin system by using a magnetic-field pulse enables magnetic resonance tomography2.

Cellulose nanocrystals (CNC) are an emerging natural material with the ability to stabilize fluid/fluid interfaces. Native CNC is hydrophilic and does not change the inter- facial tension of the stabilized emulsion or foam system. In this study, rod-like cellulose particles were isolated from hemp and chemically modified to alter their hydrophobicity, i.e. their surface-activity, which was demonstrated by surface tension measurements of the particles at the air/water interface.

We present a soft x-ray angle-resolved photoemission spectroscopy study of overdoped high- temperature superconductors. In-plane and out-of-plane components of the Fermi surface are mapped by varying the photoemission angle and the incident photon energy. No k_z dispersion is observed along the nodal direction, whereas a significant antinodal k_z dispersion is identified for La-based cuprates.

Determining the fate of the Pauling entropy in the classical spin ice material Dy₂Ti₂O₇ with respect to the third law of thermodynamics has become an important test case for understanding the existence and stability of ice-rule states in general. The standard model of spin ice—the dipolar spin ice model—predicts an ordering transition at T ≈ 0.15K, but recent experiments by Pomaranski et al.

Two-dimensional magnetic systems with continuous spin degrees of freedom exhibit a rich spectrum of thermal behaviour due to the strong competition between fluctuations and correlations. When such systems incorporate coupling via the anisotropic dipolar interaction, a discrete symmetry emerges, which can be spontaneously broken leading to a low-temperature ordered phase.

Magnetic skyrmions are topologically protected spin-whirls currently considered as promising for use in ultra-dense memory devices. Towards achieving this goal, exploration of the skyrmion phase response and under external stimuli is urgently required.

We report an inelastic neutron scattering study on the spin resonance in the bilayer iron-based superconductor CaKFe₄As₄. In contrast to its quasi-two-dimensional electron structure, three strongly L-dependent modes of spin resonance are found below T_c = 35 K.

Muon spin relaxation (μSR) experiments on a single molecule magnet enriched in different Dy isotopes detect unambiguously a slowing down of the zero field spin dynamics for the non-magnetic isotope. This occurs in the low temperature regime dominated by quantum tunnelling, in agreement with previous ac susceptibility investigations. In contrast to the latter, however, μSR is sensitive to all fluctuation modes affecting the lifetime of the spin levels.

The rational design of the magnetic anisotropy of molecular materials constitutes a goal of primary importance in molecular magnetism. Indeed, the applications of molecular nanomagnets, such as single-molecule magnets and molecular magnetic refrigerants, depend on the full control over this property.

We have observed the spatial distribution of magnetic flux in Nb, Cu/Nb, and Cu/Nb/Co thin films using muon-spin rotation. In an isolated 50-nm-thick Nb film, we find a weak flux expulsion (Meissner effect) which becomes significantly enhanced when adding an adjacent 40 nm layer of Cu. The added Cu layer exhibits a Meissner effect (due to induced superconducting pairs) and is at least as effective as the Nb to expel flux.

Temperature-pressure phase diagram of the Kitaev hyperhoneycomb iridate β-Li₂IrO₃ is explored using magnetization, thermal expansion, magnetostriction, and muon spin rotation measurements, as well as single-crystal x-ray diffraction under pressure and ab initio calculations.

The observation of Higgs boson production in association with a top quark-antiquark pair is reported, based on a combined analysis of proton-proton collision data at center-of-mass energies of √s = 7,8, and 13 TeV, corresponding to integrated luminosities of up to 5.1, 19.7, and 35.9 fb^-1, respectively. The data were collected with the CMS detector at the CERN LHC.

Staked-in needle pre-fillable syringes (SIN-PFS) are a convenient delivery system widely established in the growing pharmaceutical market. Under specific storage conditions, the needle of PFS containing high concentration drug product (DP) solution is prone to clogging, which prevents administration of the liquid.

The description and detection of unconventional magnetic states, such as spin liquids, is a recurring topic in condensed matter physics. While much of the efforts have traditionally been directed at geometrically frustrated antiferromagnets, recent studies reveal that systems featuring competing antiferromagnetic and ferromagnetic interactions are also promising candidate materials.

The material α−RuCl₃ continues to garner attention as the current poster child for realising the Kitaev model. New work places recent experimental observations on a solid theoretical footing, and concludes that the physics of α−RuCl₃ is not dominated by Kitaev interactions.

Since the seminal ideas of Berezinskii, Kosterlitz and Thouless, topological excitations have been at the heart of our understanding of a whole novel class of phase transitions. In most cases, those transitions are controlled by a single type of topological objects. There are, however, some situations, still poorly understood, where two dual topological excitations fight to control the phase diagram and the transition.