Operando spectroscopy

We develop spectroscopy and diffraction capabilities (cells, modulation experiments, time-resolved experiments, etc.) for in situ and operando analysis of catalysts and functional materials in gas and liquid environments.

We use IR, Raman and UV-vis spectroscopies as well as synchrotron based methods such as X-ray diffraction, X-ray absorption and emission spectroscopies to obtain complementary information on the catalyst structure and the adsorbates under reaction conditions. We cooperate tightly with the Center for Operando Spectroscopy Studies of PSI, which operates the SuperXAS beamline at SLS.

marchionni_acscatal_ga

Influence of CO on dry CH4 oxidation on Pd/Al2O3 by operando spectroscopy: A multitechnique modulated excitation study

V. Marchionni, M. Nachtegaal, D. Ferri, ACS Catal., 10 (2020) 4791

J. Synchr. Rad. 2020

Fluorescence detected quick scanning X-ray absorption spectroscopy

A.H. Clark, P. Steiger, B. Bornmann, S. Hitz, R. Frahm, D. Ferri, M. Nachtegaal,  J. Synchr. Rad., 27 (2020) 681

nuguid_emissioncontrol

Design of a reactor cell for modulated excitation Raman and diffuse-reflectance studies of selective catalytic reduction catalysts

R.J.G. Nuguid, D. Ferri, O. Kröcher, Em. Control Sci. Technol., 5 (2019) 307

GA Nature Catalysis 2018

The power of transient experimentation: Time-resolved copper speciation during selective catalytic reduction of NO on Cu-SSZ-13

Marberger, A., Petrov, A.W., Steiger, P., Elsener, M., Kröcher, O., Nachtegaal, M., Ferri, D., Nature Catal., 1 (2018) 221