Scientific Highlights

By combining a scalable cutting-edge synthesis method with time-resolved X-ray absorption spectroscopy measurements, it was possible to capture the dynamic local electronic and geometric structure during realistic operando conditions for highly active OER perovskite nanocatalysts.

Lignin is a major constituent of plants, and may be used as a precursor for fuels and fine chemicals. Catalytic fast pyrolysis of lignin is one of the most promising approaches. By using vacuum ultraviolet synchrotron radiation and threshold photoelectron spectroscopy we could identify elusive intermediates, which are responsible for the formation of phenol and benzene and could thus tackle this reaction mechanism. Mechanistic understanding could enable targeted improvement of production methods in the future, beyond the currently used "cook-and-look" approach.

A very thin layer on this beetle’s wings exhibits a complicated structure on the nanoscale that gives them a bright white color. X-ray nanotomography acquired at the Swiss Light Source provides a faithful image of this structure in three dimensions with which scientists can confirm its evolutionary optimization: just enough material for an efficient reflection of white light.

Online combustion analysis relies heavily on spectral data to detect reactive intermediates isomer-selectively to establish e.g. kinetic flame models. Due to the difficulty to generate these species cleanly, spectral data are rather scarce. Here we report on the selective generation of three picolyl radical isomers (C₅H₄N-CH₂*) by deamination of aminomethylpyridines. Picolyl radicals are relevant in biofuel combustion, and could now be characterized by threshold photoelectron spectroscopy using synchrotron radiation. Vibrationally resolved bands and distinct ionization energies allow for isomer-specific detection of these elusive species in complex environments and permit us to explore new avenues in soot- and NOx formation kinetics.

Researchers from China and USA join forces with Swiss Light Source (SLS) macromolecular crystallography (MX) beamline scientists in a study, which aims at understanding an important step in the life cycle of the human betacoronavirus HKU1.

A novel type of diffractive lenses based on interlaced structures enable x-ray imaging at resolutions below 10 nm. The fabrication method and the test results of these novel x-ray lenses have been published in the journal Scientific Reports.

Single holmium atoms adsorbed on few monolayers of magnesium oxide are extraordinarily stable magnets. They retain a significant fraction of their magnetization when the external magnetic field is switched off. This has been shown recently in a study combining x-ray magnetic circular dichroism performed at the Swiss Light Source (SLS) and at the European Synchrotron Radiation Facility (ESRF) as well as scanning tunneling microscopy. The results open perspectives of storing and processing information at ultrahigh density.

The first example of an insulating phase which is close to the superconducting phase in an iron-pnictide system has been recently observed in heavy Cu-doped NaFe_1-xCuxAs (x > 0.3). A combined study by angle-resolved photoemission spectroscopy (ARPES) and density functional theory (DFT) calculations revealed that on-site Coulomb repulsion and enhanced Hund’s rule coupling are responsible for the insulating behavior. The results show that the insulating phase in NaFe_0.5Cu_0.5As resembles the situation in the parent compounds of the high-T_c cuprate superconductors.

Researchers from PSI and EPFL have demonstrated that the magnetization hysteresis and remanence of TbPc₂ single-molecule magnets drastically depends on the substrate on which they are deposited. If a few atomic layers thick magnesium oxide film grown on a silver substrate is used, a record wide hysteresis and record large remanence can be obtained. Single-molecule magnets are attractive for molecular spintronics applications such as information processing or storage.

Researchers have overcome a number of challenges in order to employ an advanced probe in the study of an unusual material, barium bismuth oxide (BaBiO3) – an insulating parent compound of a family of high-temperature superconductors known since the late 80s. In order to finally realize the experiments, the researchers grew and studied thin films of the material completely in situ under ultrahigh vacuum conditions. The results show that superconductivity in bismuth oxides emerges out of a novel insulating phase, where hole pairs located on combinations of the oxygen orbitals are coupled with distortions of the crystal lattice.

Researchers at the Paul Scherrer Institute's Swiss Light Source in Villigen, Switzerland, have developed an X-ray grating interferometry setup which does not require an analyzer grating, by directly detecting the fringes generated by the phase grating with a high resolution detector. The 25um pitch GOTTHARD microstrip detector utilizes a direct conversion sensor in which the charge generated from a single absorbed photon is collected by more than one channel. Therefore it is possible to interpolate to achieve a position resolution finer than the strip pitch.

The answer to this question could save food industry a lot of money and reduce food waste caused by faulty production. Researchers from the University of Copenhagen and the Paul Scherrer Institut have obtained a 3D image of food on the nanoscale using ptychographic X-ray computed tomography. This work paves the way towards a more detailed knowledge of the structure of complex food systems.

The Angle Resolved Photoemission Spectroscopy (ARPES) measurements performed on 2DEL at STO surface revealed that, at low carrier density, electrons are always accompanied by a quantized dynamic lattice deformation. Together with the electron, these phonon-cloud formed a new composite quasiparticle called Fröhlich polaron.

The diet in many developing countries is lacking zinc, but researchers have just solved the riddle of how to get more zinc into crop seeds. The discovery has been published in Nature Plants, and the research was led by University of Copenhagen.By Johanne Uhrenholt Kusnitzoff

In order to understand limitations in current battery materials and systematically engineer better ones, it is helpful to be able to directly visualize the lithium dynamics in materials during battery charge and discharge. Researchers at ETH Zurich and Paul Scherrer Institute have demonstrated a way to do this.

Using an assembly of colloidal nanocrystals a Ag-PbS nanocomposite was produced with increased thermoelectic figures of merit up to 1.7K at 850 K. EXAFS spectroscopy at the Ag K-edge was essential to show that Ag does not dissolve in PbS nanoparticles but preserved the individual nanodomains. This reduces the PbS intergrain energy barriers for charge transport

The discovery of exceptionally well-preserved, tiny fossil seeds dating back to the Early Cretaceous corroborates that flowering plants were small opportunistic colonizers at that time, according to a new Yale-led study.

The determination of the mass density of cellular compartments is one of the many analytical tools that biologists need to unravel the extremely complex structure of biological systems. Cryo X-ray nanotomography reveals absolute mass density maps of frozen hydrated cells in three dimensions.

The macromolecular crystallography beamline X06SA at the Swiss Light Source, a synchrotron operated by Paul Scherrer Institute, is the first one in the world to upgrade its detector to an EIGER X 16M.

The study of nontrivial topological semimetals (TSM) is an emerging subject, providing a new frontier in topological aspects beyond insulators. Here, we have investigated the spin texture of surface Fermi arcs in the recently discovered Weyl semimetal TaAs using spin- and angle-resolved photoemission spectroscopy. The experimental results demonstrate that the Fermi arcs are spin polarized. The measured spin texture fulfills the requirement of mirror and time-reversal symmetries and is well reproduced by our first-principles calculations, which gives strong evidence for the topologically nontrivial Weyl semimetal state in TaAs. The consistency between the experimental and calculated results further confirms the distribution of chirality of the Weyl nodes determined by first principles calculations.

At the PEARL beamline, metal-supported ultrathin oxide films have been studied which are a class of materials of technological importance in various research fields such as catalysis, spintronics, or nanoelectronics.

Polymer solar cells are in the spotlight for sustainable energy production of the future. Characterization of these devices by X-ray nanotomography helps to improve their production using environmentally friendly materials.