SINQ Publication Highlights

We report ac susceptibility, specific heat, and neutron scattering measurements on a dipolar-coupled antiferromagnet LiYbF₄. For the thermal transition, the order-parameter critical exponent is found to be 0.20(1) and the specific-heat critical exponent −0.25(1). The exponents agree with the 2D XY/h₄ universality class despite the lack of apparent two-dimensionality in the structure.

Understanding when a material crystallizes is of fundamental importance in condensed matter. In many materials, the presence of point defects suppresses crystallization. Surprisingly, colloidal hydrogels can overcome this limitation: A small number of large microgels can spontaneously deswell to fit in the crystal lattice of smaller microgels, thus avoiding the occurrence of point defects.

Semifluorinated alkanes form monolayers with interesting properties at the air–water interface due to their pronounced amphi-solvophobic nature and the stiffness of the fluorocarbons. In the present work, using a combination of structural and dynamic probes, we investigated how small molecular changes can be used to control the properties of such an interface, in particular its organization, rheology, and reversibility during compression–expansion cycles.

PbCuTe₂O₆ is a rare example of a spin liquid candidate featuring a three-dimensional magnetic lattice. Strong geometric frustration arises from the dominant antiferromagnetic interaction that generates a hyperkagome network of Cu²⁺ ions although additional interactions enhance the magnetic lattice connectivity.

Polyelectrolyte multilayers (PEMs) with stratification of the internal structure were assembled from statistical amphiphilic copolyelectrolytes of opposite charges. These polyelectrolytes organize in aqueous solutions into micellar structures with fluoroalkyl and aromatic nanodomains, respectively, that were also preserved after deposition as thin films via layer-by-layer (LbL) electrostatic self-assembly.

We show using detailed magnetic and thermodynamic studies and theoretical calculations that the ground state of Ba₃ZnIr₂O₉ is a realization of a novel spin-orbital liquid state. Our results reveal that Ba₃ZnIr₂O₉ with Ir⁵⁺ (5d⁴) ions and strong spin-orbit coupling (SOC) arrives very close to the elusive J 1⁄4 0 state but each Ir ion still possesses a weak moment.

The phase behavior of nanoparticle (silica)−polymer (polyethylene glycol) system without and with an electrolyte (NaCl) has been studied. It is observed that nanoparticle−polymer system behaves very differently in the presence of electrolyte. In the absence of electrolyte, the nanoparticle−polymer system remains in one-phase even at very high polymer concentrations.

The mechanical performance of materials at oil/water interfaces after consumption is a key factor affecting hydrophobic drug release. In this study, we methylated the surface of nanocrystalline cellulose (NCC) by mercerization and dimethyl sulfate exposure to produce thermosensitive biopolymers. These methylated NCC (metNCC) were used to investigate interfacial thermogelation at air/water and medium-chain triglyceride (MCT)/water interfaces at body temperature.

The present Letter reports on self-diffusion in amorphous silicon. Experiments were done on ²⁹Si/^natSi heterostructures using neutron reflectometry and secondary ion mass spectrometry. The diffusivities follow the Arrhenius law in the temperature range between 550 and 700°C with an activation energy of (4.4 ± 0.3) eV.

The performance and degree of efficiency of industrial transformers are directly influenced by the magnetic properties of high-permeability steel laminations (HPSLs). Industrial transformer cores are built of stacks of single HPSLs. While the insulating coating on each HPSL reduces eddy-current losses in the transformer core, the coating also induces favorable inter-granular tensile stresses that significantly influence the underlying magnetic domain structure.

Alike materials in the solid state, the phase diagram of type-II superconductors exhibit crystalline, amorphous, liquid and spatially inhomogeneous phases. The multitude of different phases of vortex matter has thence proven to act as almost ideal model system for the study of both the underlying properties of superconductivity but also of general phenomena such as domain nucleation and morphology.

Thin plasma polymer films were deposited in hexamethyldisiloxane (HMDSO) and HMDSO/O₂ low-pressure discharges and their chemical structures analyzed using infrared (IR) spectroscopy and neutron reflectometry (NR). The (plasma-polymerized) ppHMDSO film exhibits hydrophobic, poly(dimethylsiloxane)-like properties, while the retention of carbon groups is reduced by O₂ addition, yielding a more inorganic, hydrophilic ppSiO_x film.

Following the early prediction of the skyrmion lattice (SkL) - a periodic array of spin vortices - it has been observed recently in various magnetic crystals mostly with chiral structure. Although non-chiral but polar crystals with C_nv symmetry were identified as ideal SkL hosts in pioneering theoretical studies, this archetype of SkL has remained experimentally unexplored.

We report the low-temperature magnetic properties of Ce₂Sn₂O₇, a rare-earth pyrochlore. Our suscep- tibility and magnetization measurements show that due to the thermal isolation of a Kramers doublet ground state, Ce₂Sn₂O₇ has Ising-like magnetic moments of ∼1.18 μ_B. The magnetic moments are confined to the local trigonal axes, as in a spin ice, but the exchange interactions are antiferromagnetic.

Skyrmions, topologically protected vortex-like nanometric spin textures in magnets, have been attracting increasing attention for emergent electromagnetic responses and possible technological applications for spintronics. In particular, metallic magnets with chiral and cubic/tetragonal crystal structure may have high potential to host skyrmions that can be driven by low electrical current excitation.

Motifs of periodic modulations are encountered in a variety of natural systems, where at least two rival states are present. In strongly correlated electron systems, such behaviour has typically been associated with competition between short- and long-range interactions, for example, between exchange and dipole-dipole interactions in the case of ferromagnetic thin films.

Materials with broad absorption bands are highly desirable for electromagnetic filtering and processing applications, especially if the absorption can be externally controlled. Here, a new class of broadband-absorption materials is introduced. Namely, layered metamagnets exhibit an electromagnetic excitation continuum in the magnetic-field-induced mixed ferro- and antiferromagnetic phase.

We use nuclear magnetic resonance (NMR), high-resolution x-ray, and neutron scattering studies to study structural and magnetic phase transitions in phosphorus-doped BaFe₂(As_1-xP_x)₂. Previous transport, NMR, specific heat, and magnetic penetration depth measurements have provided compelling evidence for the presence of a quantum critical point (QCP) near optimal superconductivity at x=0.3.

Inhomogeneity in the ground state is an intriguing, emergent phenomenon in magnetism. Recently, it has been observed in the magnetostructural channel of the geometrically frustrated α-NaMnO₂, for the first time in the absence of active charge degrees of freedom. Here we report an in-depth numerical and local-probe experimental study of the isostructural sister compound CuMnO₂ that emphasizes and provides an explanation for the crucial differences between the two systems.

We have studied the magnetic and superconducting properties of Ba(Fe_0.95Co_0.05)₂As₂ as a function of temperature and external magnetic field using neutron scattering and muon spin rotation. Below the superconducting transition temperature the magnetic and superconducting order parameters coexist and compete. A magnetic field can significantly enhance the magnetic scattering in the superconducting state, roughly doubling the Bragg intensity at 13.5T.

Quantum magnets have occupied the fertile ground between many-body theory and low-temperature experiments on real materials since the early days of quantum mechanics. However, our understanding of even deceptively simple systems of interacting spin-1/2 particles is far from complete. The quantum square-lattice Heisenberg antiferromagnet, for example, exhibits a striking anomaly of hitherto unknown origin in its magnetic excitation spectrum.