CNM - Publication Highlights

With a specific stimulus, shape‐memory materials can assume a temporary shape and subsequently recover their original shape, a functionality that renders them relevant for applications in fields such as biomedicine, aerospace, and wearable electronics. Shape‐memory in polymers and composites is usually achieved by exploiting a thermal transition to program a temporary shape and subsequently recover the original shape.

The properties of ligand protected gold nanoparticles are determined by the synergistic interplay of their structural components, including the metal core, the ligand shell, and the solvation layer. However, the simultaneous characterization of all these components remains a major challenge given their disparate chemical nature.

The Kondo effect, an eminent manifestation of many-body physics in condensed matter, is traditionally explained as exchange scattering of conduction electrons on a spinful impurity in a metal. The resulting screening of the impurity's local moment by the electron Fermi sea is characterized by a Kondo temperature T_K, below which the system enters a strongly coupled regime.

Elementary excitations in condensed matter capture the complex many-body dynamics of interacting basic entities in a simple quasiparticle picture. In magnetic systems the most established quasiparticles are magnons, collective excitations that reside in ordered spin structures, and spinons, their fractional counterparts that emerge in disordered, yet correlated spin states.

We report on magnetization M(H), dc and ac magnetic susceptibility Χ(T), specific heat C_m(T) and muon spin relaxation (μSR) measurements of the Kitaev honeycomb iridate Cu₂IrO₃ with quenched disorder. In spite of the chemical disorders, we find no indication of spin glass down to 260 mK from the C_m(T) and μSR data.

Water is a ubiquitous liquid with unique physicochemical properties, whose nature has shaped our planet and life as we know it. Water in restricted geometries has different properties than in bulk. Confinement can prevent low-temperature crystalliza- tion of the molecules into a hexagonal structure and thus create a state of amorphous water. To understand the survival of life at subzero temperatures, it is essential to elucidate this behaviour in the presence of nanoconfining lipidic membranes.

Magnetically coupled nanomagnets have multiple applications in nonvolatile memories, logic gates, and sensors. The most effective couplings have been found to occur between the magnetic layers in a vertical stack. We achieved strong coupling of laterally adjacent nanomagnets using the interfacial Dzyaloshinskii-Moriya interaction. This coupling is mediated by chiral domain walls between out-of-plane and in-plane magnetic regions and dominates the behavior of nanomagnets below a critical size.

Controlling the assembly of colloids in dispersion is a fundamental approach toward the production of functional materials. Nanocrystalline cellulose (NCC) is a charged nanoparticle whose colloidal interactions can be modulated from repulsive to attractive by increasing ionic strength.

Electronic systems with flat bands are predicted to be a fertile ground for hosting emergent phenomena including unconven- tional magnetism and superconductivity, but materials that manifest this feature are rare. Here, we use scanning tunnelling microscopy to elucidate the atomically resolved electronic states and their magnetic response in the kagome magnet Co₃Sn₂S₂.

Understanding and controlling the electronic structure of thin layers of quantum materials is a crucial first step towards designing heterostructures where new phases and phenomena, including the metal-insulator transition (MIT), emerge. Here, we demonstrate control of the MIT via tuning electronic bandwidth and local site environment through selection of the number of atomic layers deposited.

In this paper, we use dynamic light scattering in polarized and depolarized modes to determine the translational and rotational diffusion coefficients of concentrated rodlike cellulose nanocrystals in aqueous suspension. Within the range of studied concentrations (1–5 wt %), the suspension starts a phase transition from an isotropic to an anisotropic state as shown by polarized light microscopy and viscosity measurements.

We show, by solving Maxwell’s equations, that an electric charge on the surface of a slab of a linear magnetoelectric material generates an image magnetic monopole below the surface provided that the magnetoelectric has a diagonal component in its magnetoelectric response. The image monopole, in turn, generates an ideal monopolar magnetic field outside of the slab.

Gamma-ray bursts (GRBs) are the strongest explosions in the Universe since the Big Bang. They are believed to be produced either in the formation of black holes at the end of massive star evolution or the merging of compact objects.

To trace the origin of time-reversal symmetry breaking (TRSB) in Re-based superconductors, we performed comparative muon-spin rotation and relaxation (μSR) studies of superconducting noncentro-symmetric Re_0.82Nb_0.18 (T_c=8.8 K) and centrosymmetric Re (T_c=2.7 K).

Transition metal dichalcogenides (TMDs) are interesting for understanding the fundamental physics of two-dimensional (2D) materials as well as for applications to many emerging technologies, including spin electronics.

We report the first observation of the parity-violating gamma-ray asymmetry A_γ^np in neutron-proton capture using polarized cold neutrons incident on a liquid parahydrogen target at the Spallation Neutron Source at Oak Ridge National Laboratory.

Although ferromagnetism is known to be of enormous importance, the exploitation of materials with a compensated (for example, antiferromagnetic) arrangement of long-range ordered magnetic moments is still in its infancy. Antiferromagnetism is more robust against external perturbations, exhibits ultrafast responses of the spin system and is key to phenomena such as exchange bias, magnetically induced ferroelectricity or certain magnetoresistance phenomena.

A viable hydrogen economy has thus far been hampered by the lack of convenient hydrogen storage solutions for long hauls and transportation/delivery infrastructure. Current approaches require high pressure and/or complex heat management systems to achieve acceptable storage densities. Development of hydrogen storage solutions operating at near ambient conditions can mitigate the complexity, cost and safety perception issues currently hindering the hydrogen economy.

Multiple-q spin order, i.e., a spin texture characterized by a multiple number of coexisting magnetic modulation vec- tors q, has recently attracted attention as a source of nontrivial magnetic topology and associated emergent phenome- na. One typical example is the triple-q skyrmion lattice state stabilized by Dzyaloshinskii-Moriya interactions in noncentrosymmetric magnets, while the emergence of various multiple-q states of different origins is expected according to the latest theories.

Nanocrystalline cellulose (NCC) is a promising biological nanoparticle for the stabilization of fluid interfaces, which is however poorly understood due to the inability to form controlled NCC interfacial layers. Herein we present parameters that allow the adsorption of unmodified NCC at the air-water (A/W) interface. Initial NCC adsorption is limited by diffusion, followed by monolayer saturation and decrease in surface tension at the time scale of hours.

Coupling between dynamical heterogeneity of ionic liquids and their structural periodicity on different length-scales can be directly probed by quasielastic neutron scattering with polarization analysis. The technique provides the tools to investigate single-particle and cooperative ion motions separately and, thus, dynamics of ion associations affecting the net charge transport can be experimentally explored.

Scattering experiments establish the partly disordered material CsNiCrF₆ as the first verified example of a charge ice — and show that it supports Coulomb phases with correlations in three different degrees of freedom.

In insulating materials with ordered magnetic spiral phases, ferroelectricity can emerge owing to the breaking of in- version symmetry. This property is of both fundamental and practical interest, particularly with a view to exploiting it in low-power electronic devices. Advances toward technological applications have been hindered, however, by the rel- atively low ordering temperatures T_spiral of most magnetic spiral phases, which rarely exceed 100 K.

We report significant photoelectrochemical activity of Y-doped BiFeO₃ (Y-BFO) epitaxial thin films deposited on Nb:SrTiO₃ substrates. The Y-BFO photoanodes exhibit a strong dependence of the photocurrent values on the thickness of the films, and implicitly on the induced epitaxial strain.

The mobility of magnetic domains forms the link between the basic physical properties of a magnetic material and its global characteristics such as permeability and saturation field. Most commonly, surface domain structure are studied using magneto-optical Kerr microscopy. The limited information depth of approx. 20 nanometers, however, allows only for an indirect interpretation of the internal volume domain structures.

Coordination complexes of magnesium borohydride show promising properties as solid electrolytes for magnesium ion batteries and warrant a thorough microscopic description of factors governing their mobility properties. Here, the dynamics of Mg(BH₄)₂-diglyme_0.5 on the atomic level are investigated by means of quasielastic neutron scattering supported by density functional theory calculations and IR and NMR spectroscopy.

The Coulomb phase is an idealized state of matter whose properties are determined by factors beyond conventional consid- erations of symmetry, including global topology, conservation laws and emergent order. Theoretically, Coulomb phases occur in ice-type systems such as water ice and spin ice; in dimer models; and in certain spin liquids. However, apart from ice-type systems, more general experimental examples are very scarce.

The geometry of magnetic flux penetration in a high temperature superconductor at a buried interface was imaged using element-specific x-ray excited luminescence. We performed low tem- perature observation of the flux penetration in YBa₂Cu₃O_7–δ (YBCO) at a buried interface by imaging of the perpendicular magnetization component in square Permalloy (Py) mesostructures patterned superjacent to a YBCO film.

Using soft x-ray angle-resolved photoemission spectroscopy we probed the bulk electronic structure of T_d-MoTe₂. We found that on-site Coulomb interaction leads to a Lifshitz transition, which is essential for a precise description of the electronic structure. A hybrid Weyl semimetal state with a pair of energy bands touching at both type-I and type-II Weyl nodes is indicated by comparing the experimental data with theoretical calculations.

The Mermin–Wagner theorem has long told us that in two dimensions a continuous symmetry can be broken, allowing a finite order parameter, only at zero temperature. Now PSI theorist Bruce Normand, working with colleagues in Aachen, Amsterdam, Lausanne and Paris, has circumvented this rule. The team was considering the thermodynamics