Highlights of PSI-FELLOW Collaborations resulting in Publications

Scientists have demonstrated in a combined theoretical and experimental effort that the new ligand-field density functional theory method (LF-DFT) can be used to calculate the X-ray absorption spectra (XAS) and X-ray magnetic circular dichroism (XMCD) of lanthanide compounds from purely structural input.

Understanding and controlling the electronic structure of thin layers of quantum materials is a crucial first step towards designing heterostructures where new phases and phenomena, including the metal-insulator transition (MIT), emerge. Here, we demonstrate control of the MIT via tuning electronic bandwidth and local site environment through selection of the number of atomic layers deposited.

In insulating materials with ordered magnetic spiral phases, ferroelectricity can emerge owing to the breaking of in- version symmetry. This property is of both fundamental and practical interest, particularly with a view to exploiting it in low-power electronic devices. Advances toward technological applications have been hindered, however, by the rel- atively low ordering temperatures T_spiral of most magnetic spiral phases, which rarely exceed 100 K.

The geometry of magnetic flux penetration in a high temperature superconductor at a buried interface was imaged using element-specific x-ray excited luminescence. We performed low tem- perature observation of the flux penetration in YBa₂Cu₃O_7–δ (YBCO) at a buried interface by imaging of the perpendicular magnetization component in square Permalloy (Py) mesostructures patterned superjacent to a YBCO film.

Our experiments, published in the September issue of Structural Dynamics, demonstrate the feasibility of time-resolved pump-multiprobe X-ray diffraction experiments on protein crystals using a split-and-delay setup which was temporarily installed at the LCLS X-ray Free Electron Laser.

We report an extraordinary pressure dependence of the magnetic interactions in the metal-organic system [CuF₂(H₂O)₂]₂ pyrazine. At zero pressure, this material realizes a quasi-two-dimensional spin-1/2 square-lattice Heisenberg antiferromagnet. By high-pressure, high-field susceptibility measurements we show that the dominant exchange parameter is reduced continuously by a factor of 2 on compression.

Two-dimensional magnetic systems with continuous spin degrees of freedom exhibit a rich spectrum of thermal behaviour due to the strong competition between fluctuations and correlations. When such systems incorporate coupling via the anisotropic dipolar interaction, a discrete symmetry emerges, which can be spontaneously broken leading to a low-temperature ordered phase.

The spot size of a Fresnel Zone Plate lens is mainly determined by the zone widths of its outermost zone. It is therefore essential to fabricate zone plates with structures as small as possible for high-resolution X-ray microscopy. Researchers at the Laboratory for Micro- and Nanotechnology at the PSI have now developed Fresnel zone plates with zone widths well below 10 nm, down to 6.4 nm. These lenses are capable of pushing resolution in X-ray microscopy to the single-digit regime.

Classical theory predicts that supersaturated carbonate solutions consist mostly of ions and ion pairs, with a small number of larger clusters present in the solution. The population of the different sized clusters in a solution is solely defined by the cluster’s size dependent Free Energy. If clusters are large enough they serve as nucleation germs for a new solid phase. The nucleation occurs once the surface free energy barrier posed by the new solid-liquid interface is overcome by the free energy win from bulk phase growth.

PSI scientists have developed tailored diffractive X-ray optics for a free electron laser that induces an optical vortex in extreme ultraviolet radiation. The experiment facilitates the first demonstration of orbital angular momentum in radiation created by a free electron laser in the extreme ultraviolet regime, with an extraordinary clean and defined wavefront. In a collaborative effort with researchers from the FERMI free electron laser in Trieste, Italy and from the University of Nova Gorica in Slovenia, the wavefront of the intense beams carrying an orbtial angular momentum was characterized. Furthermore, a method to characterize the footprint of a focused beam from a free electron laser was refined based on ablation imprints in polymers and subsequent treatment with organic solvents. In this way, the sensitivity of the imprint method could be enhanced to a dynamic range of three orders of magnitude in a single shot.

Current-induced spin-orbit torques hold a great potential for manipulation of magnetization at ultrafast timescales. Researchers at ETH Zürich have demonstrated, using time-resolved STXM imaging at the Swiss Light Source, the influence of spin-orbit torques on the switching behaviour of Pt/Co/AlO_x nanostructured elements.

Lattice vibrations (phonons) in crystals are typically weakly interacting with the electronic and magnetic degrees of freedom, such as charge and spin fluctuations. Researchers of PSI together with collaborators from EPF Lausanne, Japan and USA discovered an unexpectedly strong coupling between lattice vibrations and spin fluctuations in the quantum magnet LiCrO₂. The observed magnetoelastic waves or electromagnons carry both electric and magnetic dipole moment.