News & Scientific Highlights

Recrystallization

Additive manufacturing of alloys with programmable microstructure and properties

Using laser powder bed fusion (LPBF) technology, we devise special processing strategies to ‘program’ the thermal stability of the as-printed alloy, such that it is possible to decide, a priori, how the material’s microstructure will evolve upon heat treatment

Tool Steel

Solidification modes during additive manufacturing

The thermal conditions during laser-based additive manufacturing are inferred from high-speed X-ray diffraction data and can be linked to a model for rapid solidification.

EBSD image of prior beta grains

Thermal cycling during 3D laser printing

High-speed in situ X-ray diffraction is used to measure temperature profiles and cooling rates during 3D printing of a a Ti-6Al-4V single-track wall.

Phase fractions in Ti-6Al-4V-3Fe

In situ alloying during additive manufacturing

In situ alloying is an effective method to engineer microstructures of additively manufactured Ti6Al4V3Fe alloys. 

Al3(Sc,Zr)

Thermal and phase evolution during laser powder bed fusion of Al-Sc-Zr elemental powder blends

The reaction of elemental scandium and zirconium powders with liquid aluminum is observed directly via operando X-ray diffraction during laser 3D printing. This work demonstrates that elemental blends can be used to create fine-grained crack-free Al-alloys and highlights the importance of feature size.

Operando radiography

Direct observation of crack formation mechanisms with operando Laser Powder Bed Fusion X-ray radiography

Operando high-speed X-ray radiography experiments reveal the cracking mechanism during 3D laser printing of a Ni superalloy.

A Three Dimensional View of Chemical Heterogeneities in Defect-Engineered HKUST-1 Crystals

Full-field X-ray absorption tomography reveals the chemical structure of defects in metal-organic frameworks

Cryo-full-field XANES computed tomography was used to visualize the presence and distribution of a second coordination polymer of reduced copper coordination within defect-engineered HKUST-1 MOF crystals. Observations encourage a revisitation of the structure-property relationships of defect-engineered MOFs.

Cover Materials Today

Operando X-ray diffraction during laser 3D printing

Ultra-fast operando X-ray diffraction experiments reveal the temporal evolution of low and high temperature phases and the formation of residual stresses during laser 3D printing of a Ti-6Al-4V alloy. The profound influence of the length of the laser-scanning vector  on the evolving microstructure is revealed and elucidated.  

inside batteries

Inside Batteries

Lithium ion batteries (LIB) are essential in modern everyday life, with increasing interest in enhancing their performance and lifetime. Secondary particles of Li-rich cathode material were examined with correlated ptychographic X-ray tomography and diffraction microscopy at different stages of cycling to probe the aging mechanism.

Figure 1 (a) Transient relative x-ray intensity of the (1.5 0.5 0.5) superlattice reflection of Sr0.97Ca0.03TiO3 upon above bandgap excitation with 40 fs pulses Inset: STO crystal structure as seen along the c-axis. phi measures the antiferrodistortive rotation of the oxygen octahedra (exaggerated) and represents the order parameter. (b) Calculated energy change per STO cubic unit cell as a function of oxygen displacement u/u0 along the in-plane cubic crystal axes resulting from the octahedral rotation at …

Moving Atoms by Photodoping

Understanding how and how fast we can drive atoms to create a structural phase transition is of fundamental interest as it directly relates to many processes in nature. Here we show that a photoexcitation can drive a purely structural phase transition before the energy is relaxed in the material that corresponds to a “warmer” equilibrated state.

Schematic representation of the active state of a Pt-Ni bimetallic nano-particle on the silica surface with unreduced nickel ions in/on silicates of the support.

Active Sites of supported bimetallic nano-Catalysts

Dynamic Structural Changes of Active Sites in Pt–Ni Bimetallic Catalysts Revealed by a Multimodal Approach

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HERCULES at the Swiss Light Source

In the week of March 18-23 PSI welcomes 20 PhD students and postdocs taking part in the HERCULES 2018 school on Neutron and Synchrotron Radiation. They will attend lectures and perform two days of practical courses at several beam lines of the Swiss Light Source.

Making the world go round - a look into the structure of a prominent heterogeneous catalyst

Fluid catalytic cracking catalysts, which are composite particles of hierarchical porosity, were examined using ptychographic X-ray tomography. These particles are essential to the conversion of crude oil into gasoline. Examination of catalysts at decreasing levels of catalytic conversion efficacy allowed the detection of possible deactivation causes.

Chemical Imaging to Spy on Malaria Parasites

Unique insights into the adolescence and metabolism of a Malaria parasite in a human red blood cell are obtained by a new chemical imaging methodology – in situ correlative X-ray fluorescence microscopy and soft X-ray tomography.

Fate of Plutonium through a Geological Reactive Barrier

Natural geological and engineered barriers play a key role in protecting the environment and the anthroposphere from the hazardous impact of deposited waste or spreading contaminants. Such natural geological and engineered barrier materials are commonly complex and heterogeneous. In-situ multimodal microscopic studies under conditions relevant to deep geological formations are crucial to identify the reactive components and reaction pathways or to validate proposed immobilization mechanisms. The present study demonstrated that a simplistic description by a sole reactive component is not an adequate representation of the geochemical reactivity responsible for the immobilization of plutonium within a natural Clay Rock barrier. Multimodal chemical imaging studies on intact, undisturbed systems are absolutely essential to ascertain the geochemical reactivity for relevant geochemical conditions and settings.

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Detecting and utilizing minority phases in heterogeneous catalysis

Highly active phases in carbon monoxide oxidation are known, however they are transient in nature. Here, we determined for the first time the structure of such a highly active phase on platinum nanoparticles in an actual reactor.

The chemical state of 79Se in spent nuclear fuel

An interdisciplinary study conducted at different PSI laboratories (LES,AHL, LRS, SYN) in collaboration with Studsvik AB (Sweden) demonstrates that selenium originating from fission in light water reactors is tightly bound in the crystal lattice of UO2. This finding has positive consequences for the safety assessment of high-level radioactive waste repository planned in Switzerland, as it implies (contrary to previous assumptions) that the safety-relevant radionuclide 79Se will be released at extremely low rates during aqueous corrosion of the waste in a deep-seated repository.By Enzo Curti (PSI-LES)

The diet in many developing countries is lacking zinc, but researchers have just solved the riddle of how to get more zinc into crop seeds. The discovery has been published in Nature Plants, and the research was led by University of Copenhagen. Above picture shows microscopic chemical images of a cross-section through a mutant seed. From left to right and top to bottom: Ca, P, Fe, Zn, MnCaFe, S, K, Cu, Mn. Image courtesy of C. Larue, Uni. Toulouse. Data collected at microXAS (Swiss Light Source). Scale bar

Researchers find key to zinc rich plants to combat malnutrition

The diet in many developing countries is lacking zinc, but researchers have just solved the riddle of how to get more zinc into crop seeds. The discovery has been published in Nature Plants, and the research was led by University of Copenhagen.By Johanne Uhrenholt Kusnitzoff

Watching lithium move in battery materials

In order to understand limitations in current battery materials and systematically engineer better ones, it is helpful to be able to directly visualize the lithium dynamics in materials during battery charge and discharge. Researchers at ETH Zurich and Paul Scherrer Institute have demonstrated a way to do this.