News & Scientific Highlights

Evolution of the catalyst during the pretreatment and postulated reaction mechanism in the dry reforming of methane

In situ Study of Low-temperature Dry Reforming of Methane Over La2Ce2O7 and LaNiO3 Mixed Oxides

The combination of in situ spectroscopy methods allowed to detect the evolution of a catalyst precursor to the catalytic material, and investigate a relevant reaction. The reduction of a mixture of perovskite, pyrochlore and nickel leads to the formation of active and selective catalytst, converting carbon dioxide and methane to syngas. 

Ammonium sulfate has been used as a probe for aerosol particles and investigated in situ by means of ambient pressure X-ray photoelectron spectroscopy. Unexpectedly, when the particles start to absorb water, a spontaneous redox reaction leading to nitrogen and elemental sulfur takes place.

PUBLISHED IN SCIENCE: A surface-promoted redox reaction occurs spontaneously on solvating inorganic aerosol surfaces

Ammonium sulfate has been used as a probe for aerosol particles and investigated in situ by means of ambient pressure X-ray photoelectron spectroscopy. Unexpectedly, when the particles start to absorb water, a spontaneous redox reaction leading to nitrogen and elemental sulfur takes place.

In situ and ex situ ambient pressure X-ray photoelectron spectroscopy have been used to investigate the solid-liquid interface of a LSCO water splitting catalyst. Experimental results, supported by theoretical simulations of the core-electron binding energy, detect the formation of cobalt oxyhydroxide under working conditions.

Direct evidence of cobalt oxyhydroxide formation on a LSCO perovskite water splitting catalyst

In situ and ex situ ambient pressure X-ray photoelectron spectroscopy have been used to investigate the solid-liquid interface of a LSCO water splitting catalyst. Experimental results, supported by theoretical simulations of the core-electron binding energy, detect the formation of cobalt oxyhydroxide under working conditions. 

The evolution of atomically dispersed platinum species on ceria has been investigated by means of ambient pressure X-ray photoelectron spectroscopy and X-ray absorption near edge structure spectroscopy. Experimental results, supported by the theoretical simulation of the phase diagram, show that atomically dispersed species evolve towards nanoparticles during the activation of the catalysts. Such an evolution is influenced by the temperature and the reaction environment.

Temperature and Reaction Environment Influence the Nature of Platinum Species Supported on Ceria

The evolution of atomically dispersed platinum species on ceria has been investigated by means of ambient pressure X-ray photoelectron spectroscopy and X-ray absorption near edge structure spectroscopy. Experimental results, supported by the theoretical simulation of the phase diagram, show that atomically dispersed species evolve towards nanoparticles during the activation of the catalysts. Such an evolution is influenced by the temperature and the reaction environment. 

Enhanced reducibility of ceria influences the reaction mechanism towards CO oxidation

Enhanced Reducibility of the Ceria-Tin Oxide Solid Solution Modifies the CO Oxidation Mechanism at the Platinum-Oxide Interface

The introduction of tin into ceria strongly influences its reducibility. In turn, the reaction mechanism towards the oxidation of carbon monoxide changes: the oxidation rate increases, the apparent activation energy decreases and the reaction order in oxygen increases.

Encapsulation of highly dispersed palladium oxide clusters in the microporous channels and voids of the nanosized silicalite-1 crystals has been achieved by using an amine-based ligand

Stable Palladium Oxide Clusters Encapsulated in Silicalite-1 for Complete Methane Oxidation

Encapsulation of highly dispersed palladium oxide clusters in the microporous channels and voids of the nanosized silicalite-1 crystals has been achieved by using an amine-based ligand.

The Pt 4f photoemission signal highlights how the nanoparticles evolve as a function of the reaction environment.

The dynamics of overlayer formation on catalyst nanoparticles and strong metal-support interaction

The strong metal support interaction has been investigated in situ by means of electron microscopy, XPS and XRD, to provide a complete overview about the interplay between the metal and the support. 

Sketch showing the temperature-dependent surface segregation of Sr-containing species, and their dissolution upon immersion in water

Surface Segregation Acts as Surface Engineering for the Oxygen Evolution Reaction on Perovskite Oxides in Alkaline Media

The temperature-dependent segregation of strontium-containing species on LSCO electrodes has been studied by means of XPS, SEM and XRD. Such surface species dissolve almost quantitatively upon immersion in water, leaving cobalt oxide, the active site of the reaction, free. 

Role of water in the oxidation of methane on Palladium foil

Role of water on the structure of palladium for methane complete oxidation

The mechanism of methane oxidation in the presence of water has been investigated in situ by means of APXPS. 

Kinetics of iridium thermal oxidation followed while dosing 1 mbar oxygen

Kinetics of the Thermal Oxidation of Ir(100) Studied by APXPS

The thermal oxidation of single-crystalline Ir(100) films toward rutile IrO2(110) has been investigated in situ by means of APXPS.