Research on Covid-19

At PSI, several projects are dedicated to important research questions concerning the Sars-CoV-2 coronavirus and the resulting diseases. We provide information on activities and projects, for example on investigations of lung tissue, on the production of proteins and antibodies or on ideas for new research on Covid-19.

Useful links

Anthony_July2020

Surface Segregation Acts as Surface Engineering for the Oxygen Evolution Reaction on Perovskite Oxides in Alkaline Media

La1–xSrxCoO3-δ perovskites are potential catalysts for the anodic reaction of alkaline water electrolyzers, i.e., the oxygen evolution reaction (OER). It is well-known that La1–xSrxCoO3−δ perovskites can easily display strontium surface segregation, but how this influences the performance of La1–xSrxCoO3−δ perovskites as anodic electrode in alkaline water electrolyzers, particularly in terms of OER activity, has not been unveiled yet. This study focuses on La0.2Sr0.8CoO3−δ, which shows relatively high activity for the OER, and reveals the influence of the preparation temperature on the amount and morphology of segregated strontium-containing islands. Thin film samples were prepared at different temperatures by using pulsed laser deposition. Those samples were then characterized with synchrotron-based X-ray photoelectron spectroscopy “as prepared” and after being immersed in ultrapure water. We found that higher preparation temperatures enhance the segregation of strontium, which is then almost quantitatively removed by washing the samples with ultrapure water. After immersion in water, the samples expose a cobalt-rich surface. Investigating the OER activity as a function of the perovskite deposition temperature, it has been found that the higher the deposition temperature (i.e., the more extended the strontium segregation), the higher the OER activity. Such an effect has been linked to the higher amount of cobalt accessible after removing the strontium segregated islands.

Sketch showing the temperature-dependent surface segregation of Sr-containing species, and their dissolution upon immersion in water

Surface Segregation Acts as Surface Engineering for the Oxygen Evolution Reaction on Perovskite Oxides in Alkaline Media

The temperature-dependent segregation of strontium-containing species on LSCO electrodes has been studied by means of XPS, SEM and XRD. Such surface species dissolve almost quantitatively upon immersion in water, leaving cobalt oxide, the active site of the reaction, free. 

Shang et al

Simultaneous Nodal Superconductivity and Time-Reversal Symmetry Breaking in the Noncentrosymmetric Superconductor CaPtAs

By employing a series of experimental techniques, we provide clear evidence that CaPtAs represents a rare example of a noncentrosymmetric superconductor which simultaneously exhibits nodes in the superconducting gap and broken time-reversal symmetry (TRS) in its superconducting state (belowTc ≈ 1.5 K). Unlike in fully gapped superconductors, the magnetic penetration depth λ(T) does not saturate at low temperatures, but instead it shows a T2 dependence, characteristic of gap nodes.

Dikic lab

First MX results of the priority COVID-19 call

The Dikic group at the Goethe University in Frankfurt am Main, Germany has published the first results following the opening of the "PRIORITY COVID-19 Call” at SLS. 

zabilskiy_nature_comm_2020.jpg

The unique interplay between copper and zinc during catalytic carbon dioxide hydrogenation to methanol

The nature of high activity of Cu/ZnO catalyst in methanol synthesis remains the subject of intensive debate. Here, the authors are revisiting carbon dioxide hydrogenation mechanism using high-pressure operando techniques.

CuPCP jet in the Prime chamber

Publication of the very first Pilot experiment results from Alvra

The results from the first pilot experiment at Alvra have just been published in Nature Communications. The measurements probed the excited-state character of a Cu-P OLED complex using X-ray emission spectroscopy from the phosphorus atoms in the molecule.

E Coli

Photobiocatalytic H2 evolution of GaN:ZnO and [FeFe]-hydrogenase recombinant Escherichia coli

The need for sustainable, renewable and low-cost approaches is a driving force behind the development of solar-to-H2 conversion technologies. This study aims to develop a new strategy using a visible-light photocatalyst coupled to a biocatalyst for H2 production. Photocatalytic methyl viologen (MV2+) reduction activity was investigated to discover active oxynitrides. In comparative studies with LaTiO2N, BaTaO2N and Ta3N5, it was revealed that the suitable surface area, band gap and band edge potentials are some physical factors that are responsible for the photocatalytic behaviors of GaN:ZnO in MV2+ reduction. The activity is enhanced at higher concentrations and the alkaline pH of triethanolamine (TEOA). The expression of an active [FeFe]-hydrogenase from Escherichia coli (Hyd+E. coli) as a recombinant biocatalyst was confirmed by its MV˙+-dependent H2 production activity. In the photobiocatalytic system of GaN:ZnO and Hyd+E. coli, the rate of H2 production reached the maximum level in the presence of MV2+ as an electron mediator at neutral pH as a biocompatible condition. The present work reveals a novel hybrid system for H2 production using visible-light active GaN:ZnO coupled to Hyd+E. coli, which shows the feasibility of being developed for photobiocatalytic H2 evolution under solar light.

Lehrberufe à la carte 2020

Am Sonntag, 21. Juni 2020 ist abgesagt!

Cover Materials Today

Operando X-ray diffraction during laser 3D printing

Ultra-fast operando X-ray diffraction experiments reveal the temporal evolution of low and high temperature phases and the formation of residual stresses during laser 3D printing of a Ti-6Al-4V alloy. The profound influence of the length of the laser-scanning vector  on the evolving microstructure is revealed and elucidated.  

Grinenko et al

Superconductivity with broken time-reversal symmetry inside a superconducting s-wave state

In general, magnetism and superconductivity are antagonistic to each other. However, there are several families of superconductors in which superconductivity coexists with magnetism, and a few examples are known where the superconductivity itself induces spontaneous magnetism. The best known of these compounds are Sr2RuO4 and some non-centrosymmetric superconductors. Here, we report the finding of ...

Pionic helium teaser

Laser focus on mesons

The first demonstration of laser spectroscopy of a meson, achieved at PSI's πE5 beamline, opens up new avenues for precision studies of ‘exotic atoms’.

Roboter

Was tut eine angehende Physiklaborantin im Homeoffice?

Sie entwickelt zum Beispiel einen autonomen und fernsteuerbaren Roboter und erweitert so ihre Erfahrungen in Mess-, Steuer- und Regeltechnik und vertieft ihre Kenntnisse in der Programmierung. Eine Lernende des 2. Lehrjahres beschreibt hier, wie es ihr dabei ergangen ist.

Benefit of random testing

Benefit of random testing

With the imminent relaxation of socio-economic restrictions, it becomes vital to assess its effect on the prevalence of acute infections within the population, as rapidly as possible. Currently available monitoring instruments for the COVID-19 pandemic have an inherent time delay of about 14 days, as they rely on confirmed infections, hospitalizations, and death numbers. These methods give Reff(t) (the number of infections caused by a single infected person), but their delay is a significant disadvantage when restrictions are released. If after relaxation, Reff(t) rises above 1, one will not be able to react adequately before two weeks have passed during which time the prevalence could significantly rise. Here, we propose the use of random testing to shorten this reaction time, by obtaining direct and modeling dependent information on Reff(t). Through random testing of between 2500 and 20000 people per day, we find that over periods significantly shorter than two weeks, it becomes possible to detect a dangerous increase in Reff with reasonable confidence.

3D rendering of an anti-tube

Miniaturized fluidic circuitry observed in 3D

The team of Prof. Thomas Hermans at the University of Strasbourg in France managed to create wall-less aqueous liquid channels called anti-tubes. Thanks to X-ray phase contrast tomography at the TOMCAT beamline those anti-tubes could be observed in 3D. The exciting results were published in Nature on May 6, 2020.

Information for SmuS, SINQ and CHRISP users

The restart of operating the PSI high intensity proton accelerator (HIPA) is expected to be delayed by about 2 months due to the Corona virus situation. The pandemic team of PSI approved a scenario where in-house research at the correponding facilities will be possible from mid of July on. External users at HIPA will only be allowed as of September 1st.

This means that we have to shift many .....

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Taking a snapshot of the triplet excited state of an OLED organometallic luminophore using X-rays

In this work, the complementarity of pump-probe experiments at SwissFEL (ALVRA endstation) and at synchrotrons (SuperXAS beamline of SLS and ID09 of ESRF) is used to investigate the triplet excited state of Cu OLED materials. Details about the charge transfer and structural rearrangements in the excited state of this material are revealed and obtained data can be used to verify computational methods for rational development of new OLED materials.

Zoom Collaboration Meeting

Virtual Collaboration Meeting

During the Corona crisis, meetings are only possible online. The Mu3 collaboration met today virtually with more than 20 people from three different countries.

Han purple

Understanding Quantum Critical Magnetism in Han Purple

The ancient purple pigment used to paint the terracotta warriors, BaCuSi2O6, is also a quantum magnetic material which consists of stacked Cu2+ bilayers hosting spin dimers. Magnetometry and NMR experiments have revealed puzzling critical phenomena at the quantum phase transition (QPT) caused by an applied magnetic field, which suggest that the universal behaviour of the system is not three- but only two-dimensional. By performing high-resolution neutron spectroscopy measurements .....

 

Abisoliergerät

Den «Funken im Griff»

Eine andere Variante Mantel-Thermoelemente abisolieren zu können.

Support during Corona

On this page, you will find helpful tools and links for families and others who need to combine care work and home office during Corona. The current circumstances considerably influence our way of working.

Atomic structure of 2D materials

2D Materials

Hexagonal boron nitride (h-BN) “nanomesh”, a two-dimensional insulating monolayer, grown on the (111) surface of rhodium exhibits an intriguing hexagonal corrugation pattern with a lattice constant of 3.2 nm.

CMS 2020

Measurement of properties of Bs0 → μ+μ− decays and search for B0 → μ+μ− with the CMS experiment

Results are reported for the B0s → μ+μ branching fraction and effective lifetime and from a search for the decay B0 → μ+μ−. The analysis uses a data sample of proton-proton collisions accumulated by the CMS experiment in 2011, 2012, and 2016, with center-of-mass energies (integrated luminosities) of 7TeV (5fb−1), 8TeV (20fb−1),and 13TeV (36fb−1).