Energy transition

Shifting away from nuclear energy, expanding solar and wind power, generating energy from biomass, reducing energy consumption. Switzerland is committed to becoming climate-neutral by 2050. An ambitious goal, which has become more urgent than ever due to the increasingly challenging geopolitical situation. How can a sustainable and resilient energy supply for Switzerland be established over the coming years? What's the optimal way to use renewable energy sources? What new technologies are especially promising? At PSI, researchers are seeking answers to these crucial questions.

First EIGER X 16M in operation at the Swiss Light Source

The macromolecular crystallography beamline X06SA at the Swiss Light Source, a synchrotron operated by Paul Scherrer Institute, is the first one in the world to upgrade its detector to an EIGER X 16M.

Demonstration of the flip-over effect. As a consequence of using a non-circular laser spot, the longest direction of the laser spot results in the shortest direction of the deposition pattern and vice versa.

The flip-over effect in pulsed laser deposition: Is it relevant at high background gas pressures?

In pulsed laser deposition the use of a rectangular or elliptical beam spot with a non 1:1 aspect ratio leads to the so called flip-over effect. Here, the longest dimension of the laser spot results in the shortest direction of plasma plume expansion.

Nanostructure surveys of macroscopic specimens by small-angle scattering tensor tomography

The mechanical properties of many materials are based on the macroscopic arrangement and orientation of their nanostructure. This nanostructure can be ordered over a range of length scales. In biology, the principle of hierarchical ordering is often used to maximize functionality, such as strength and robustness of the material, while minimizing weight and energy cost.

Aluminium X-ray absorption near-edge spectroscopy analysis of discoloured ultramarine blue in 20th century oil paintings

A specific case of synthetic ultramarine degradation was observed in three oil paintings from the early 20th century. Pigment particleswere found to have been discoloured, resulting in intricate patterns ofwhite lines, approximately 10 to 30 microns wide, criss-crossing the paint surface. Colour in ultramarine pigments comes from the encapsulated sulphur radical anions, chromophores, inside the cage framework built from SiO4 4 − and AlO4 5 −

Schematic of a Weyl semimetal with spin polarized Fermi arcs on its surfaces connecting the projections of two Weyl nodes with opposite chirality.

Observation of Fermi-Arc Spin Texture in TaAs

The study of nontrivial topological semimetals (TSM) is an emerging subject, providing a new frontier in topological aspects beyond insulators. Here, we have investigated the spin texture of surface Fermi arcs in the recently discovered Weyl semimetal TaAs using spin- and angle-resolved photoemission spectroscopy. The experimental results demonstrate that the Fermi arcs are spin polarized. The measured spin texture fulfills the requirement of mirror and time-reversal symmetries and is well reproduced by our first-principles calculations, which gives strong evidence for the topologically nontrivial Weyl semimetal state in TaAs. The consistency between the experimental and calculated results further confirms the distribution of chirality of the Weyl nodes determined by first principles calculations.

Schematic of layer-specific electronic states in the bulk band gap of ultrathin magnesium oxide at the metal/oxide and the oxide/vacuum interfaces.

Excited states at interfaces of a metal-supported ultrathin oxide film

At the PEARL beamline, metal-supported ultrathin oxide films have been studied which are a class of materials of technological importance in various research fields such as catalysis, spintronics, or nanoelectronics.

Schlussveranstaltung

Nationaler Zukunftstag 2015

Am Nationalen Zukunftstag 2015 durften wir 55 Mädchen und 56 Jungs am PSI begrüssen. Die 111 Kinder konnten aus den angebotenen 11 Stationen (Berech¬nungs-ingenieur, Chemieingenieure, Chemielaboranten, Elektroniker, Fachfrauen Betreuung, Metallographen, Physiker, Physiklaboranten, Strukturbiologen, Techn. Laborassistenten und iLab), jeweils zwei auswählen und diese beiden an einem halben Tag besichtigen.

X-ray nanotomography aids the production of eco-friendly solar cells

Polymer solar cells are in the spotlight for sustainable energy production of the future. Characterization of these devices by X-ray nanotomography helps to improve their production using environmentally friendly materials.

Strong enhancement of s-wave superconductivity near a quantum critical point of Ca3Ir4Sn13

We report microscopic studies by muon spin rotation/relaxation as a function of pressure of the Ca3Ir4Sn13 and Sr3Ir4Sn13 cubic compounds, which are members of the (Ca1−xSrx)3Ir4Sn13 system displaying superconductivity and a structural phase transition associated with the formation of a charge density wave (CDW).

Hydrogen atoms are light and can tunnel through a barrier. Tunnelling can be quenched by substituting them with deuterium, a twice as heavy isotope of H.

Controlling tunnelling in methane loss from acetone ions by deuteration

At the imaging Photoelectron Photoion Coincidence (iPEPICO) endstation of the VUV beamline evidence of H-atom tunneling was shown.

Direct evidence for a pressure-induced nodal superconducting gap in the Ba0.65Rb0.35Fe2As2 superconductor

The superconducting gap structure in iron-based high-temperature superconductors (Fe-HTSs) is non-universal. In contrast to other unconventional superconductors, in the Fe-HTSs both d-wave and extended s-wave pairing symmetries are close in energy. Probing the proximity between these very different superconducting states and identifying experi- mental parameters that can tune them is of central interest.

Intrinsic Paramagnetic Meissner Effect Due to s-Wave Odd-Frequency Superconductivity

In 1933, Meissner and Ochsenfeld reported the expulsion of magnetic flux - the diamagnetic Meissner effect - from the interior of superconducting lead. This discovery was crucial in formulating the Bardeen-Cooper-Schrieffer (BCS) theory of superconductivity. In exotic superconducting systems BCS theory does not strictly apply.

New EU project: Guiding light for the world's brightest light sources

EUCALL will build bridges between major laser and X-ray research centres: For the past half-century, two special kinds of light have changed the landscape of research. Advanced visible-spectrum optical lasers have propelled studies into ultrafast processes, new materials, telecommunications, and many other fields, while intense X-rays produced at synchrotrons have helped image tiny structures and otherwise invisible parts of matter, enabling huge leaps in biochemistry, pharmacology, and materials science. New developments have enhanced the generation of X-rays at optical-laser and accelerator facilities, resulting in the creation of large international research centres. The European Union is now funding a 7 million-euro effort to bring these research centres together through the European Cluster of Advanced Laser Light Sources (EUCALL) project.

Visualizing the morphology of vortex lattice domains in a bulk type-II superconductor

Alike materials in the solid state, the phase diagram of type-II superconductors exhibit crystalline, amorphous, liquid and spatially inhomogeneous phases. The multitude of different phases of vortex matter has thence proven to act as almost ideal model system for the study of both the underlying properties of superconductivity but also of general phenomena such as domain nucleation and morphology.

Visualizing the morphology of vortex lattice domains in a bulk type-II superconductor

Alike materials in the solid state, the phase diagram of type-II superconductors exhibit crystalline, amorphous, liquid and spatially inhomogeneous phases. The multitude of different phases of vortex matter has thence proven to act as almost ideal model system for the study of both the underlying properties of superconductivity but also of general phenomena such as domain nucleation and morphology.

Put in perspective

Researchers from the Paul Scherrer Institute PSI have succeeded in using commercially available camera technology to visualise terahertz light. In doing so, they are enabling a low-cost alternative to the procedure available to date, whilst simultaneously increasing the comparative image resolution by a factor of 25. The special properties of terahertz light make it potentially advantageous for many applications, from safety technology to medical diagnostics.

Top: High-pressure CH4 adsorption isotherms (AIs). The usable capacity for a classical Langmuir-type AI (top left) and a ‘stepped’ AI (top middle), with the minimum desorption pressure and the maximum adsorption pressure indicated by the vertical lines. Right, CH4 AIs for Co(bdp)  at 25 °C with Pdes = 5.8 bar and Pads = 35 bar indicated by dashed lines and filled/open circles representing adsorption/desorption.  Middle: The crystal structures of the collapsed (0bar) and CH4- expanded (30bar CH4) phases of …

Methane storage in flexible metal–organic frameworks with intrinsic thermal management

As a cleaner, cheaper, and more globally evenly distributed fuel, natural gas has considerable environmental, economic, and political advantages over petroleum as a source of energy for the transportation sector. Despite these benefits, its low volumetric energy density at ambient temperature and moderate pressure presents substantial challenges, particularly for light-duty vehicles with little space available for on-board fuel storage.

Obtained XFEL radiation profiles for two different radiation wavelengths using the multiple-slotted foil technique: 1Å (blue plots) and 5 Å (magenta plots). For each case we have run 5 simulations using different seeds for the generation of the shot noise of the electron beam. Radiation pulses of about 1 TW and rms length of about 200 as can be generated in 80 m of undulator line for a radiation wavelength of 1Å and in about 40 m for a wavelength of 5 Å.

New methods to generate short and high-power X-ray Free-Electron-Laser pulses

State-of-the-art X-ray Free-Electron-Laser (XFEL) facilities like SwissFEL are able to provide radiation pulses with pulse powers of a few tens of gigawatts and pulse durations of several tens of femtoseconds and shorter. There is, however, a strong demand in research fields such as bioimaging and nonlinear optics to obtain higher radiation powers and shorter pulses than in standard facilities. In this context, we have developed two new methods able to generate terawatt-attosecond XFEL pulses. Both proposals are based on superradiance, a regime with quadratic growth of the radiation power and a shortening of the spike while it slips into unspoiled (good-beam) regions of the bunch.

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Room-temperature carbon monoxide oxidation by oxygen over Pt-Al2O3 mediated by reactive platinum carbonates

A new possibility for the attainment of low-temperature oxidation of carbon monoxide is demonstrated. Here we report using time-resolved DRIFTS, XAS, and mass spectrometry a platinum carbonate-mediated mechanism for the room-temperature oxidation of carbon monoxide.

Sketch of the different stacking configuration of the bilayers and the corresponding total magnetization measured. Reprinted with permission from Nano Lett., 15 (11), pp 7355–7361 (2015) . Copyright 2015 American Chemical Society

Interfacial Control of Magnetic Properties at LaMnO3/LaNiO3 heterostructures

Using a X-ray magnetic circular dichroism measured at the X-Treme beamline, SLS, in conjunction with X-ray reflectivity measured at the SEXTANTS beamline, SOLEIL, the authors show that the degree of intermixing at the monolayer scale allows interface-driven properties such as charge transfer and the induced magnetic moment in the nickelate layer to be controlled.

Figure caption: Sketch of the 3D Fermi surface of d-AlNiCo (left) and its experimental cross-sections in the indicated planes (right) showing vanishing pseudogap in the quasiperiodic directions.

Fermi states and anisotropy of Brillouin zone scattering in the decagonal Al–Ni–Co quasicrystal

Quasicrystals (QCs) are intermetallic alloys where excellent long-range order coexists with lack of translational symmetry in one or more dimensions. These materials have a high potential in application as a material for a solar cells, hydrogen storage applications, heat insulating layers, and others.

Observation of Gravitationally Induced Vertical Striation of Polarized Ultracold Neutrons by Spin-Echo Spectroscopy

We describe a spin-echo method for ultracold neutrons (UCNs) confined in a precession chamber and exposed to a |B0| = 1μT magnetic field. We have demonstrated that the analysis of UCN spin-echo resonance signals in combination with knowledge of the ambient magnetic field provides an excellent method by which to reconstruct the energy spectrum of a confined ensemble of neutrons.

Response of Plasma-Polymerized Hexamethyldisiloxane Films to Aqueous Environments

Thin plasma polymer films were deposited in hexamethyldisiloxane (HMDSO) and HMDSO/O2 low-pressure discharges and their chemical structures analyzed using infrared (IR) spectroscopy and neutron reflectometry (NR). The (plasma-polymerized) ppHMDSO film exhibits hydrophobic, poly(dimethylsiloxane)-like properties, while the retention of carbon groups is reduced by O2 addition, yielding a more inorganic, hydrophilic ppSiOx film.