Rechargeable batteries that last longer and recharge more rapidly

It’s not necessary to re-invent the rechargeable battery in order to improve its performance. As Claire Villevieille, head of the battery materials research group at the Paul Scherrer Institute PSI says: In the context of this competitive field, most researchers concentrate on the development of new materials. In cooperation with colleagues at the ETH in Zurich, Villevieille and co-researcher Juliette Billaud took a different approach: We checked existing components with a view to fully exploiting their potential. Simply by optimizing the graphite anode – or negative electrode - on a conventional Li-ion battery, researchers were able to boost battery performance. Under laboratory conditions, we were able to enhance storage capacity by a factor of up to 3. Owing to their complex construction, commercial batteries will not be able to fully replicate these results. But performance will definitely be enhanced, perhaps by as much as 30 – 50 percent: further experiments should yield more accurate prognoses.

Researchers point out that in terms of industrial implementation, improving existing components has the great advantage of requiring less developmental input than a new battery design using new materials. As Villevieille says: We already have everything we need. If a manufacturer were willing to take on production, enhanced batteries could be ready for the market within one or two years. The procedure is simple, cost-effective and scalable for use on rechargeable batteries in all areas of application, from wristwatch to smartphone, from laptop to car. And it has the additional bonus of being transferable to other anode-cathode batteries such as those based on sodium.

Arranging the flakes

In this case, changing the way anodes work was the key to success. Anodes are made from graphite, i.e. carbon, arranged in tiny, densely packed flakes, comparable in appearance to dark grey cornflakes haphazardly compressed, as in a granola bar. When a Li-ion battery is charging, lithium ions pass from the cathode, or positive metal oxide electrode, through an electrolyte fluid to the anode, where they are stored in the graphite bar. When the battery is in use and thus discharging, the lithium ions pass back to the cathode but are forced to take many detours through the densely packed mass of graphite flakes, compromising battery performance.

These detours are largely avoidable if the flakes are arranged vertically during the anode production process so that they are massed parallel to one another, pointing from the electrode plane in the direction of the cathode. Adapting a method already used in the production of synthetic composite materials, this alignment was achieved by André Studart and a team of research experts in the field of material nanostructuration at the ETH Zurich. The method involves coating the graphite flakes with nanoparticles of iron oxide sensitive to a magnetic field and suspending them in ethanol. The suspended and already magnetized flakes are subsequently subjected to a magnetic field of 100 millitesla—about the strength of a fridge magnet. André Studart explains that by rotating the magnet during this process, the platelets not only align vertically but in parallel formation to one another, like books on a shelf. As a result, they are perfectly ordered, reducing the diffusion distances covered by the lithium ions to a minimum.

Shorter paths for the ions

Microscopic images show that if the magnet remains turned on during the ensuing drying process, the platelets keep their new orientation even when removed from the ethanol suspension. Instead of their formerly haphazard arrangement, the flakes in the compressed graphite bar are now parallel, enabling the lithium ions to flow much more easily and quickly, whilst also increasing storage capacity by allowing more ions to dock during the charging process. Claire Villevieille emphasizes that the chemical composition of batteries remains the same. The remaining iron oxide nanoparticles are negligible in quantity and do not influence battery function. All we did was optimise the anode structure.

Text: Jan Berndorff

About PSI

The Paul Scherrer Institute PSI develops, builds and operates large, complex research facilities and makes them available to the national and international research community. The institute's own key research priorities are in the fields of matter and materials, energy and environment and human health. PSI is committed to the training of future generations. Therefore about one quarter of our staff are post-docs, post-graduates or apprentices. Altogether PSI employs 2000 people, thus being the largest research institute in Switzerland. The annual budget amounts to approximately CHF 370 million. PSI is part of the ETH Domain, with the other members being the two Swiss Federal Institutes of Technology, ETH Zurich and EPFL Lausanne, as well as Eawag (Swiss Federal Institute of Aquatic Science and Technology), Empa (Swiss Federal Laboratories for Materials Science and Technology) and WSL (Swiss Federal Institute for Forest, Snow and Landscape Research).

(Stand 05/2016)