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Mass Density and Water Content of Saturated Never-Dried Calcium Silicate Hydrates

Calcium silicate hydrates (C-S-H) are the most abundant hydration products in ordinary Portland cement paste. Yet, despite the critical role they play in determining mechanical and transport properties, there is still a debate about their density and exact composition. Here, the site-specific mass density and composition of C-S-H in hydrated cement paste are determined with nanoscale resolution in a nondestructive approach.

Table-top soft x-ray laser delivering circularly polarized femtosecond pulses

Table-top soft x-ray lasers based on high-order harmonic generation (HHG)

Table-top soft x-ray lasers based on high-order harmonic generation (HHG) deliver routinely linearly polarized light. Many advanced applications including magnetic imaging would profit from a HHG source delivering in addition circular polarized light. In one of our recent work we present now an approach which provides intense soft x-ray radiation of high ellipticity. This source has given us the opportunity to realize the first magnetic dichroism experiment on a nickel sample at 18 nm (67 eV) with a table-top HHG source.

Magnetic inhomogeneity on a triangular lattice: the magnetic-exchange versus the elastic energy and the role of disorder

Inhomogeneity in the ground state is an intriguing, emergent phenomenon in magnetism. Recently, it has been observed in the magnetostructural channel of the geometrically frustrated α-NaMnO2, for the first time in the absence of active charge degrees of freedom. Here we report an in-depth numerical and local-probe experimental study of the isostructural sister compound CuMnO2 that emphasizes and provides an explanation for the crucial differences between the two systems.

PSI-Feriencamp 2015

Suchen Sie für Ihr Kind ein spannendes Angebot während den Sommerferien? Möchten Sie in ihm die Neugier und Begeisterung für naturwissenschaftlich-technische Themen wecken? Die Berufsbildung und das Komitee für Chancengleichheit führt dieses Jahr zum achten Mal das PSI-Feriencamp durch!

C-band structures in the clean room next to the area in which the stacking and brazing takes place

Successful start of the series production of the C-band accelerating structures for SwissFEL

A total of 104 C-band accelerating structures will be needed for SwissFEL. Each of these structures is about 2 m long and consists out of 113 copper cells that are manufactured with micrometer precision using ultra-precision diamond machining, which results in mirror-like surfaces. The main components are the couplers at the input and the output of the structure, and the copper disks. For both, couplers and disks, the series production was successfully launched at the end of 2014. Since then the Dutch company VDL and TEL Mechatronics in Trübbach, Switzerland, delivered already many sets of couplers and accelerating disks, respectively.

Interfacial dominated ferromagnetism in nanograined ZnO: a μSR and DFT study

Diamagnetic oxides can, under certain conditions, become ferromagnetic at room temperature and therefore are promising candidates for future material in spintronic devices. Contrary to early predictions, doping ZnO with uniformly distributed magnetic ions is not essential to obtain ferromagnetic samples. Instead, the nanostructure seems to play the key role, as room temperature ferromagnetism was also found in nanograined, undoped ZnO.

Non-Fermi Liquid Behavior Close to a Quantum Critical Point in a Ferromagnetic State without Local Moments

A quantum critical point (QCP) occurs upon chemical doping of the weak itinerant ferromagnet Sc3.1In. Remarkable for a system with no local moments, the QCP is accompanied by non-Fermi liquid behavior, manifested in the logarithmic divergence of the specific heat both in the ferro-and the paramagnetic states, as well as linear temperature dependence of the low-temperature resistivity.

Surface Aligned Magnetic Moments and Hysteresis of an Endohedral Single-Molecule Magnet on a Metal

The interaction between the endohedral unit in the single-molecule magnet Dy2ScN@C80 and a rhodium (111) substrate leads to alignment of the Dy 4f orbitals. The resulting orientation of the Dy2ScN plane parallel to the surface is inferred from comparison of the angular anisotropy of x-ray absorption spectra and multiplet calculations in the corresponding ligand field.

Prospective studies for SwissFEL experiments done at the SLS FEMTO station

For many years, PSI researchers have been testing experimental methods that will provide insights into novel materials for electronic devices. Using a special trick to make the Swiss Light Source (SLS) at PSI generate light with similar properties to that of PSI's x-ray laser SwissFEL, the researchers were able to demonstrate that the experiments planned for SwissFEL are possible and they are now building an experimental station at SwissFEL. read the full story)

Muonium in Stishovite: Implications for the Possible Existence of Neutral Atomic Hydrogen in the Earth's Deep Mantle

Hydrogen in the Earth's deep interior has been thought to exist as a hydroxyl group in high-pressure minerals. We present Muon Spin Rotation experiments on SiO2 stishovite, which is an archetypal high-pressure mineral. Positive muon (which can be considered as a light isotope of proton) implanted in stishovite was found to capture electron to form muonium (corresponding to neutral hydrogen).

Magnetic inhomogeneity on a triangular lattice: the magnetic-exchange versus the elastic energy and the role of disorder

Inhomogeneity in the ground state is an intriguing, emergent phenomenon in magnetism. Recently, it has been observed in the magnetostructural channel of the geometrically frustrated α-NaMnO2, for the first time in the absence of active charge degrees of freedom. Here we report an in-depth numerical and local-probe experimental study of the isostructural sister compound CuMnO2 that emphasizes and provides an explanation for the crucial differences between the two systems.

Left: Structure of BaFe2As2 with the motion pattern of the A1g phonon mode (red arrows). 
Right: Pump-induced change of diffraction intensity of the (1 0 5) reflection

Ultrafast structural dynamics of the Fe-pnictide parent compound BaFe2As2

Understanding the interplay of the various degrees of freedom such as the electrons, spins and lattice is essential for many complex materials, including the high-temperature superconductors.

Pressure dependence of the magnetic order in CrAs

The suppression of magnetic order with pressure concomitant with the appearance of pressure-induced superconductivity was recently discovered in CrAs. Here we present a neutron diffraction study of the pressure evolution of the helimagnetic ground state towards and in the vicinity of the superconducting phase. Neutron diffraction on polycrystalline CrAs was employed from zero pressure to 0.65 GPa and at various temperatures.

Pressure dependence of the magnetic order in CrAs

L. Keller et al., Phys. Rev. B 91, 020409(R) (2015). The suppression of magnetic order with pressure concomitant with the appearance of pressure-induced superconductivity was recently discovered in CrAs. Here we present a neutron diffraction study of the pressure evolution of the helimagnetic ground state towards and in the vicinity of the superconducting phase. Neutron diffraction on polycrystalline CrAs was employed from zero pressure to 0.65 GPa and at various temperatures.

The phase diagram of electron-doped La2-xCexCuO4-δ

Superconductivity is a striking example of a quantum phenomenon in which electrons move coherently over macroscopic distances without scattering. The high-temperature superconducting oxides (cuprates) are the most studied class of superconductors, composed of two-dimensional CuO2 planes separated by other layers that control the electron concentration in the planes. A key unresolved issue in cuprates is the relationship between superconductivity and magnetism.

Quantitatively Probing the Al Distribution in Zeolites

The degree of substitution of Si4+ by Al3+ in the oxygen-terminated tetrahedra (Al T-sites) of zeolites determines the concentration of ion-exchange and Brønsted acid sites. Because the location of the tetrahedra and the associated subtle variations in bond angles influence the acid strength, quantitative information about Al T-sites in the framework is critical to rationalize catalytic properties and to design new catalysts.

Quantitatively Probing the Al Distribution in Zeolites

The degree of substitution of Si4+ by Al3+ in the oxygen-terminated tetrahedra (Al T-sites) of zeolites determines the concentration of ion-exchange and Brønsted acid sites. Because the location of the tetrahedra and the associated subtle variations in bond angles influence the acid strength, quantitative information about Al T-sites in the framework is critical to rationalize catalytic properties and to design new catalysts.

Terahertz spot size before (left) and after (right) wavefront optimization

Terahertz wavefront control for extremely bright THz bullet

The brightness of a light source defines its applicability to nonlinear phenomena in science. The SwissFEL laser group has now overcome one of the two principal technological hurdles to produce bright pulses in the Terahertz range (0.1-5 THz).

Competing superconducting and magnetic order parameters and field-induced magnetism in electron-doped Ba(Fe1-xCox)2As2

We have studied the magnetic and superconducting properties of Ba(Fe0.95Co0.05)2As2 as a function of temperature and external magnetic field using neutron scattering and muon spin rotation. Below the superconducting transition temperature the magnetic and superconducting order parameters coexist and compete. A magnetic field can significantly enhance the magnetic scattering in the superconducting state, roughly doubling the Bragg intensity at 13.5T.

Magnetization dynamics inside a 5 µm x 5 µm structure.(a) Time-resolved PEEM images using XMCD as a magnetic contrast mechanism recorded at a given time delay t after the laser pulse and (b) extracted XMCD contrast as a function of the time delay t for three different ROI, defined in the inset image by the coloured area superimposed on the non-dichroic X-ray absorption of the structure. The 0° incoming laser direction with respect to the structure edge is indicated in the inset by the laser in-plane wave v…

Nanoscale sub-100 picosecond all-optical magnetization switching in GdFeCo microstructure

Ultrafast magnetization reversal driven by femtosecond laser pulses has been shown to be a promising way to write information. Seeking to improve the recording density has raised intriguing fundamental questions about the feasibility of combining ultrafast temporal resolution with sub-wavelength spatial resolution for magnetic recording. Here we report on the experimental demonstration of nanoscale sub-100 ps all-optical magnetization switching, providing a path to sub-wavelength magnetic recording.

Magnetic moment measured by XMCD and resistivity as a funtion of temperature for two different piezostrain states

Control of Tc in La0.7Sr0.3MnO3 via piezostrain

X-ray magnetic circular dichroism measurements evidence a 10K shift of the magnetic Curie temperature for La0.7Sr0.3MnO3 deposited on the piezoelectric substrate [Pb(Mg1/3Nb2/3)O3]0.68−[PbTiO3]0.32 (011) for two different remanent piezostrain states.