Forschung zu Covid-19

Radio-frequency structures at X-band frequencies (~ 12 GHZ) are being considered for applications in compact Free Electron Lasers, medical linacs, a future linear collider (CLIC project) and as a diagnostic for measuring ultra-short (femtosecond) electron pulses in FELs. A first prototype of such a structure has been built at PSI employing the realization procedures that have been developed for the C-Band (6 GHz) structures of the SwissFEL linac.

The false coincidence background has so far limited the analytical application of PEPICO, photoelectron photoion coincidence. A new photoioin rastering technique has been developed to separate the wheat from the chaff and identify true coincidences based on the ion hit time and position. This expands the dynamic range of the experiment by at least two orders of magnitude, allowing for novel applications to look for reactive intermediates and short lived species in reaction environments.

Epitaxial thin films of the proton-conducting perovskite BaZr_0.53In_0.47O_3−δH_0.47−2δ, grown by pulsed laser deposition, were investigated in their hydrated and dehydrated conditions through a multitechnique approach with the aim to study the structure and proton concentration depth profile and their relationship to proton conductivity.

The European Cluster of Advanced Laser Light sources (EUCALL), a European Union-funded project that aims to foster links between accelerator- and laser-driven X-ray facilities, has completed the first year of its three year project period. The project successfully met all twenty of its milestones for the year, producing a new open-source tool for experiment simulations and developing specifications for several pieces of new scientific equipment.

The recent developments in scientific complementary metal oxide semiconductor (sCMOS) detector technology allow for imaging of relevant processes with very high temporal resolution with practically negligible readout time. However, it is neutron intensity that limits the high temporal resolution neutron imaging. In order to partially overcome the neutron intensity problem for the high temporal resolution imaging, a parabolic neutron focussing guide was utilized in the test arrangement and placed upstream the detector in such a manner that the focal point of the guide was positioned slightly behind the scintillator screen. In such a test arrangement, the neutron flux can be increased locally by about one order of magnitude, albeit with the reduced spatial resolution due to the increased divergence of the neutron beam. In a pilot test application, an in-situ titration system allowing for a remote delivery of well-defined volumes of liquids onto the sample stage was utilized. The process of droplets of water (H₂O) falling into the container filled with heavy water (D₂O) and the subsequent process of the interaction and mixing of the two liquids were imaged with temporal resolution of 0.01 s.

The recent improvement on the capability of neutron imaging that allows acquiring neutron images with isotropic spatial resolution of about 5 micrometres is demonstrated. This is achieve by combining the tailor-made high-numerical aperture magnifying optics together with a thin isotopically-enriched ¹⁵⁷Gd₂O₂S:Tb scintillator screens (see Trtik & Lehmann, NIM-A 788 (2015) 67-70). The newly achieved level of the spatial resolution represents about 30% enhancement compared to the first prototype (see Trtik et al, Physics Procedia 69 (2015) 169-176) and approximately six-fold enhancement in the spatial resolution capabilities available for the general users community at PSI before the start of the Neutron Microscope project.

JUNGFRAU is a charge-integrating, two-dimensional pixel detector developed at the Paul Scherrer Institut for use at free-electron lasers, in particular SwissFEL, and synchrotron light sources. On the 10th October, the first protein crystallography experiment using the JUNGFRAU detector, was performed at the beamline X06SA (PXI) of the Swiss Light Source by the members of the Protein Crystallography and Detectors groups at PSI.

The activation and conversion of hydrocarbons is one of the most important challenges in chemistry. This work shows that isolated Co(II) sites are catalysts for a number of hydrocarbon conversion reactions, such as the dehydrogenation of propane, the hydrogenation of propene, and the trimerization of terminal alkynes. The data are consistent with all of these reactions occurring by a common mechanism, involving heterolytic C–H or H–H activation via a 1,2 addition across a Co–O bond.

JUNGFRAU is a charge-integrating, two-dimensional pixel detector developed at the Paul Scherrer Institut for use at free-electron lasers, in particular SwissFEL, and synchrotron light sources. On the 10th October, the first protein crystallography experiment using the JUNGFRAU detector, was performed at the beamline X06SA (PXI) of the Swiss Light Source by the members of the Protein Crystallography and Detectors groups at PSI.

The first example of an insulating phase which is close to the superconducting phase in an iron-pnictide system has been recently observed in heavy Cu-doped NaFe_1-xCuxAs (x > 0.3). A combined study by angle-resolved photoemission spectroscopy (ARPES) and density functional theory (DFT) calculations revealed that on-site Coulomb repulsion and enhanced Hund’s rule coupling are responsible for the insulating behavior. The results show that the insulating phase in NaFe_0.5Cu_0.5As resembles the situation in the parent compounds of the high-T_c cuprate superconductors.

One of the long-lasting unsolved problems in Nuclear Astrophysics is the so-called "Cosmological Li Problem", i.e. the large discrepancy between the primordial ⁷Li abundance predicted by models of Big Bang Nucleosynthesis and the one inferred from astronomical observation. The study of the production/destruction rates of the radioactive precursor ⁷Be is one of the clues for solving this problem.

Sahan Ranamukhaarachchi, PhD student from UBC in Vancouver, won the 2016 "Brian L. Barge Award for Excellence in Microsystems Integration" for his work on a biosensing platform with integrated hollow microneedles carried out at PSI in 2015 in collaboration with Dr. Victor Cadarso and Dr. Celestino Padeste.

Pressure-induced ordering close to a z = 1 quantum-critical point is studied in the presence of bond disorder in the quantum spin system (C₄H₁₂N₂)Cu₂(Cl_1−xBr_x)₆ (PHCX) by means of muon-spin rotation and relaxation.

On Monday October the 10th the last piece of the vacuum tube was mounted and pumped down. The about 500 m long vacuum chamber from the end of the injector to the photonics front end is now under vacuum. The only missing junction at z=119m between the already operated injector and the rest of SwissFEL will be mounted shortly before the delivery of the operation permit.

On the 6th of October the last undulator for the ARAMIS beamline was placed into the SwissFEL tunnel. Thanks to the efficiency and motivation of the different groups involved with undulator preparation, all 12 undulators were assembled, measured and installed in the tunnel between the 2nd of February 2016 and the 6th of October 2016.

Multiferroic composite materials combining ferroelectric and ferromagnetic order at room temperature have great potential for emerging applications such as four-state memories, magnetoelectric sensors, and microwave devices.

The kinetics involved in novel ambient-temperature mechanism for the catalytic oxidation of carbon monoxide by oxygen over a Pt/Al2O3 catalyst is evaluated within a periodic redox operation paradigm using combined mass spectrometry (MS), diffuse reflectance infrared spectroscopy (DRIFTS), and time-resolved Pt L3-edge XAFS. A high-wavenumber (ca. 1690 cm-1) carbonate species are shown to be associated with a room-temperature redox process occurring in a fraction of the Pt atoms present in the catalyst.

In vortex-like spin arrangements, multiple spins can combine into emergent multipole moments. Such multipole moments have broken space-inversion and time-reversal symmetries, and can therefore exhibit linear magnetoelectric (ME) activity. Three types of such multipole moments are known: toroidal; monopole; and quadrupole moments. So far, however, the ME activity of these multipole moments has only been established experimentally for the toroidal moment.