Platinum chloride in aqueous solution promotes the dispersion of large gold nanoparticles (>70 nm) on carbon carriers into single atoms, forming bimetallic single-atom catalysts with improved resistance against sintering at temperatures up to 800 K and under the harsh reductive reaction conditions of acetylene hydrochlorination, leading to improved lifetime in this reaction. To rationalize these observations, this study, led by ETH Zurich, utilized X-ray adsorption spectroscopy conducted at the SuperXAS beamline of the SLS to provide insights into the degree of gold dispersion and the structure of the isolated metal sites in the bimetallic catalysts.