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publist2019.pdf

Edebeli_J_Thesis

Molecules2013.pdf

Combining SAXS and XAS To Study the Operando Degradation of Carbon-Supported Pt-Nanoparticle Fuel Cell Catalysts

In the last two decades, small-angle X-ray scattering (SAXS) and X-ray absorption spectroscopy (XAS) have evolved into two well-established techniques capable of providing complementary and operando information about a sample’s morphology and composition, respectively. Considering that operation conditions can often lead to simultaneous and related changes in a catalyst’s speciation and shape, herein we introduce a setup that combines SAXS and XAS in a configuration that allows optimum acquisition and corresponding data quality for both techniques.

Iridium Oxide for the Oxygen Evolution Reaction: Correlation between Particle Size, Morphology, and the Surface Hydroxo Layer from Operando XAS

A simple and scalable method for preparation of well-defined chlorine–free iridium oxide nanoparticles active for oxygen evolution reaction (OER) was developed. Operando X-ray absorption spectroscopy and X-ray photoelectron spectroscopy indicate that OER activity is strongly related to the presence of iridium hydroxo (Ir–OH) species on the surface of iridium oxide nanoparticles.

IrO2‑TiO2: A High-Surface-Area, Active, and Stable Electrocatalyst for the Oxygen Evolution Reaction

We have developed a synthetic approach to highsurface-area chlorine-free iridium oxide nanoparticles dispersed in titania (IrO2-TiO2), which is a highly active and stable OER catalyst in acidic media. Operando X-ray absorption studies demonstrate the evolution of the surface species as a function of the applied potential, suggesting the conversion of the initial hydroxo surface layer to the oxo-terminated surface via anodic oxidation.

Amor_NIMA_821_44.pdf

BVR50 protocol

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